You can have ‘stuff’ in a folder, mount a partition to that folder, and have disk space used for which you cannot account. Using a tool like df, you will see that 10GB of your 10GB disk is used, but using du the individual folders only account for 5GB.
Rather than randomly umounting partitions to see if there’s anything in the mount point folder, you can bind mount root to another location and check the disk utilization on the new mount.
[root@fedora123 ~]# mount -o bind / /mnt/fakeout/
[root@fedora123 ~]# du -sh `ls /mnt/fakeout | grep -v mnt`
0 bin
0 boot
280K ca
8.0K cacert.pem
4.0K careq.pem
0 certs
0 crl
0 dev
44M etc
52K home
0 index.txt
0 lib
0 lib64
0 media
0 newcerts
0 openhab
724K opt
4.0K private
0 proc
847M root
0 run
0 sbin
227M srv
0 sys
4.0K tmp
3.0G usr
4.0K var
[root@fedora123 ~]# umount fakeout